I found a couple articles/tips explaining you different ways to find out the site collection ID on your SharePoint farm.
Retrieving the Site Collection ID from SharePoint (WSS 3) Chris
A Very Fast Method to Get the Site Collection’s Web Structure
In my opinion the easiest way to find the site collection ID is through the Central Admin site. Follow the instructions below to get the site collection id.
You can find the Site Collection ID by opening the Central Administration, then opening the Application Management, and
then clicking Site Collection Administrators in the SharePoint Site Management section.
There you choose the administrators for your site collection.
The Site Collection ID shows up in the URL of the site collection selected. If you can’t find the ID change the web application and try again.
Tell me if this is the easiest way!

